Dual-Mode Lithium-Bromine Battery

Technology #16994

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(a) Exploded view of the hybrid-electrolyte fuel cell. (b) Schematic demonstration of the dual-mode operation of the fuel cell. (c) Comparison of the theoretical and practical pack-level specific energies of lithium–bromine (Li–Br2) energy systems, all vanadium redox flow battery (VRFB), zinc–bromine flow battery (Zn–Br2), LiFePO4 (LFP), zinc–air battery (Zn–O2) and lithium–sulphur battery (Li–S). Data of Li/Br2 was calculated at the solubility limit, others were taken from ref. 33.
Categories
Inventors
Professor Martin Bazant
Department of Chemical Engineering, MIT
External Link (www.mit.edu)
Peng Bai
Department of Chemical Engineering, MIT
External Link (web.mit.edu)
Venkatasubramanian Viswanathan
Department of Chemical Engineering, MIT
Managed By
Christopher Noble
MIT Technology Licensing Officer - Clean and Renewable Energy
Patent Protection

A Lithium-Bromine Rechargeable Electrochemical System and Applications Thereof

PCT Patent Application WO 2016-191551
Publications
A Dual-mode Rechargeable Lithium–Bromine/Oxygen Fuel Cell
Journal of Materials Chemistry A, 2015,3, 14165-14172

Applications

With the aid of advanced sensor and sonar capabilities, naval applications are requiring high power sources, which this technology can provide. Some naval applications requiring compact energy-dense power include submarines, missile systems, mines, torpedoes, countermeasure autonomous underwater vehicles (AUV), and sonobouys. However, by replacing seawater with hydrobromic acid or lithium bromide in water the battery can be applied to systems on land such as electric vehicles.

Problem Addressed 

Many battery applications often have endurance and surge requirements. A dual-mode lithium-bromine (Li/Br) battery can operate in two separate settings, low-power mode designed for endurance and a high-power mode designed for surge requirements.

Technology

The dual-mode battery operates by modifying or changing the catholyte. Analogous to the nitrous oxide system used in race cars, which injects N2O to provide extra oxygen to increase the power output of the internal combustion engine, the dual-mode lithium-bromine/oxygen cell allows the injection of bromine as the reaction booster to provide higher power density on demand. The cell consists of a lithium metal at the anode protected by a lithium phosphorous oxynitride (LiPON) interlayer and a lithium superionic conductor (LISICON) separator. The protection layer between the anode and the electrolyte ensures the conduction of lithium ions and blocks the flow of electrons and other reactants. The cathode reaction in low power mode is the reduction of dissolved oxygen and in the high power mode is the reduction of bromine. For the low power mode a specific energy of 428.5 Whr/kg and an energy density of 471.4 Whr/L were measures. For the how power mode, a specific energy of 791.5 Whr/kg and an energy density of 1357 Whr/L.

Advantages

  • Ability to operate at two power modes
  • Seawater electrolyte, which is ideal for naval applications
  • Electrolyte can be modified for electric vehicles