Abrasion Deposition of Carbon Nanomaterials on Patterned Substrates

Technology #16974

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Fabrication of the sensing material consists of mechanically mixing and compressing SWCNT composites into a pellet. Stepwise fabrication of fully drawn chemiresistive sensors on PMMA.
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Inventors
Professor Timothy Swager
Department of Chemistry, MIT
External Link (swagergroup.mit.edu)
Katherine Mirica
Department of Chemistry, Dartmouth College
External Link (www.miricagroup.com)
Kelvin Frazier
Department of Chemistry, MIT
Joseph Walish
Department of Chemistry, MIT
Managed By
Jim Freedman
MIT Technology Licensing Officer - Chemicals, Instruments, Consumer Products
Patent Protection

Methods and devices for deposition of materials on patterned substrates

PCT Patent Application WO 2016-029028
Publications
Fully-drawn carbon-based chemical sensors on organic and inorganic surfaces
Lab on a Chip, October 21, 2014, p. 4059–4066

Applications

This method can be used in the fabrication of sensors, circuits, and tags to make designed resistor networks on various substrates safely, easily and efficiently. It can also be extended towards the manufacturing of solar cells by making films using the abrasion method and controlling the film’s depositional properties by modifying the surface of the substrate.

Problem Addressed

Carbon-based nanomaterials, such as carbon nanotubes and graphene, are electrically conductive materials that are ideal for chemical sensing. Sensors can be fabricated in a solvent-free, portable manner via deposition of conductive carbon nanostructures using mechanical abrasion of compressed carbon-based composites on a variety of surfaces. However, the size, thickness and distribution of the resulting conductive carbon nanostructures deposited on substrates is difficult to control and limited by the features of the substrate (e.g. surface roughness and distribution of cellulose fibers on the surface of paper).

Technology

The inventors have developed a process for the deposition of conductive layers of nanocomposites by physical abrasion onto patterned surfaces. This method offers precise control over location, thickness, and other structural features of the resulting nanostructures, which greatly extends its capabilities for the fabrication of functional sensors, circuits and tags. Sensors are fabricated by abrasion of compressed single-walled carbon nanotubes (SWCNTs) and compressed graphite onto laser-etched plastic and paper. This approach produces sensors that are able to detect a wide variety of analytes in part-per-million concentrations.

Other methods, such as chemical etching, scratching, and nanoindentation can be used to generate patterns that guide abrasion of carbon-based materials into pre-defined locations. The choice of substrate includes glass, polymers of any kind, paper, metal, skin, leaves and wood, among others. This method of selective deposition of materials can be extended to small molecules, metals, nanoparticles, and conductive polymers.

Advantages

  • Enables parallel fabrication of conductive micro- and nanostructures with precise control over structural features
  • Method can be used on a wide range of substrates  
  • Simple and inexpensive fabrication without need for specialized equipment or facilities
  • Portable, efficient, eco-friendly and scalable approach